相图边界理论及其应用pdf/txt下载_在线阅读全文

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本书是英文版。本书分两部分。**部分着重介绍了作者提出的相图中若干新概念，并应用热力学原理导出了相图中对应关系定理及其推论，进一步找到了边界维数和相边界维数之间的关系，从而找到了确定相图中相邻相区及其边界的关系的若干物理量及其变化，从而可以阐述各类恒压相图中相邻相区及其边界的关系。第二部分是高压相图的边界理论及其计算。我们把恒压边界理论推广到高压相图，从而导出高压相图的边界理论及其热力学计算方法，计算了单元、二元、三元高压相图，并通过实验检验了计算的高压相图，实验相图与计算相图符合得很好。

内容简介

The Boundary Theory of Phase Diagrams and Its Application Rules forPhase Diagram Construction with Phase Regions and Their Boundariespresents a novel theory of phase diagrams. Thoroughly revised on the basisof the Chinese edition and rigorously reviewed, this book inspects thegeneral feature and structure of phase diagrams, and reveals that there existactually two categories of boundaries. This innovative boundary theoryhas solved many difficulties in understanding phase diagrams, and alsofinds its application in constructing multi-component phase diagrams orin calculating high-pressure phase diagrams. Researchers and engineers aswell as graduate students in the areas of chemistry, metallurgy and materialsscience will benefit from this book.Prof. Muyu Zhao was the recipient of the 1998 Prize for Progress in Scienceand Technology (for his work on the boundary theory of phase diagrams)awarded by the National Commission of Education, China, and many otherprizes.

作者简介

Muyu Zhao,College of Chemistry Jilin UniversityChangchun, 130012, ChinaEmail: muyuzhao1929 @yahoo.com.cn. Xiaobao Fan,Tekna Plasma Systems, Inc.Sherbrooke, CanadaEmail: xiaobao.fan @ tekna.com. Lizhu Song,College of ChemistryJilin UniversityChangchun, 130012, ChinaEmail: slz@jlu.edu.cn.

目　　录

PrefaceCommentIntroductionPart One The Phase Rule, Its Deductionand ApplicationChapter 1 The Phase Rule, Its Deduction and Application1.1 Why do We Discuss the Phase Rule at First1.2 Different Methods for Deducing the Phase Rule:The Method ofGibbs Himself,Gibbs-Roozeboom's Method and the Method of Gibbs FreeEnergy Minimization1.3 Determination of the Number of Independent Components byBrinkley＇s Method1.4 Some Remarks on the Application of the Phase RuleReferences-1Summary of Part OnePart Two The Boundary Theory of Isobaric PhaseDiagrams and ItsApplicationChapter 2The Boundary Theory of Isobaric Phase Diagrams——Rules forPhase Diagram Construction2.1 Introduction2.2 Several Basic Concepts for Underlying the Phase Diagram2.3 The Theorem of the Corresponding Relationship between the TotalNumber of All the Different Phases in NPRs φand the Dimensions ofthe Phase Boundary R1 in Phase Diagrams, and Its TheoreticalDeduction2.4 The Theorem of the Corresponding Relationship （TCR） is anIndependent Theorem, Not a Variant of the Phase Rule2.5 Corollaries of TCR for Isobaric Phase Diagrams2.6 The Relationship between the Dimensions of the Phase BoundaryR1and the Dimensions of the Boundary R1' for IsobaricMulticomponent Phase Diagrams2.7 The Summary of the Boundary Theory of Isobaric Phase DiagramsReferences-2Chapter 3 Application of the Boundary Theory to Unary, Binary andTernary Phase DiagramsComparison of the Boundary Theory Applicationand Palatnik-Landau's Contact Rule of Phase Regions3.1 Determination of Phase Assemblages of NPRs and theCharacteristics of Their Boundaries by the Boundary Theory3.2 Application of the Boundary Theory to Unary Phase Diagrams3.3 Application of the Boundary Theory to Binary Phase Diagrams3.4 Application of the Boundary Theory to Ternary Phase Diagrams3.5 Explanation of Rhines' Ten Empirical Rules for ConstructingComplicated Ternary Phase Diagrams with the Bounary Theory3.6 Comparison of the Boundary Theory and the P-L's Contact Rule ofPhase RegionsReferences-3Chapter 4The Application of the Boundary Theory of Phase Diag-rams to theQuaternary and Higher Number Component Phase Diagrams4.1 Introduction4.2 The Relationship among NPRs and their Boundaries in a Typical,Iso-baric, Quaternary Phase Diagram4.3 During Temperature Decreasing, Some Cases of Variations of theNPRsand their Boundaries, May be Encountered for Several Types ofQuaternary Isobaric Phase Diagrams4.4 The Isobaric Quinary Phase Diagrams4.5 ConclusionReferences-4Chapter 5 The Boundary Theory in Construction of Multicompo-nentIsothermal Sections5.1 The Relationship among Neighboring Phase Regions （NPRs） and Th-eir Boundaries in Isobaric Isothermal Multicomponent Sections5.2 The Non-Contact Phase Regions and the Boundaries between ThemContents5.3 Construction of an Isothermal Quinary Section, with LimitedInformation5.4 The Method of Constructing an Isothermal Eight-Componentsection5 5 Summary of Part TwoPart Three The Boundary Theory methodReferences-5Chapter 6 The Boundary Theory of Multicomponent Isobaric IsoplethSections6.1 Introduction6.2 The Characteristics of Boundaries in Isopleth Sections for theCase ofⅣ≥2 and R1≥16.3 The Characteristics of Boundaries in the Isopleth Section forthe Case of N≥2，R1=0，there is no Invariant Phase Transition betweenthe two NPRs6.4 The Case 0f N≥2，R1=0，there is an Invariant Phase Transitionbetween the two NPRs．In this Case，there may be fl,Boundary Line ora Boundary Point between two NPRs'6.5 Example6.6 The TheOrY of Two～Dimensional Sections of IsobaricMulticomponent Phase Diagrams．References-6Chapter 7 The Application of the Boundary Theory to Isobaric PhaseDiagrams7.1 Brief Review of the Application for the Boundary Theory7.2 The Analysis of the Fe-Cr-C Isopleth Section。

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<pre>
Preface
Comment
Introduction
Part One The Phase Rule, Its Deductionand Application
Chapter 1 The Phase Rule, Its Deduction and Application
1.1 Why do We Discuss the Phase Rule at First
1.2 Different Methods for Deducing the Phase Rule:The Method of
Gibbs Himself,Gibbs-Roozeboom's Method and the Method of Gibbs Free
Energy Minimization
1.3 Determination of the Number of Independent Components by
Brinkley＇s Method
1.4 Some Remarks on the Application of the Phase Rule
References-1
Summary of Part One
Part Two The Boundary Theory of Isobaric PhaseDiagrams and Its
Application
Chapter 2The Boundary Theory of Isobaric Phase Diagrams——Rules for
Phase Diagram Construction
2.1 Introduction
2.2 Several Basic Concepts for Underlying the Phase Diagram
2.3 The Theorem of the Corresponding Relationship between the Total
Number of All the Different Phases in NPRs φand the Dimensions of
the Phase Boundary R1 in Phase Diagrams, and Its Theoretical
Deduction
2.4 The Theorem of the Corresponding Relationship （TCR） is an
Independent Theorem, Not a Variant of the Phase Rule
2.5 Corollaries of TCR for Isobaric Phase Diagrams
2.6 The Relationship between the Dimensions of the Phase Boundary
R1and the Dimensions of the Boundary R1' for Isobaric
Multicomponent Phase Diagrams
2.7 The Summary of the Boundary Theory of Isobaric Phase Diagrams
References-2
Chapter 3 Application of the Boundary Theory to Unary, Binary and
Ternary Phase DiagramsComparison of the Boundary Theory Application
and Palatnik-Landau's Contact Rule of Phase Regions
3.1 Determination of Phase Assemblages of NPRs and the
Characteristics of Their Boundaries by the Boundary Theory
3.2 Application of the Boundary Theory to Unary Phase Diagrams
3.3 Application of the Boundary Theory to Binary Phase Diagrams
3.4 Application of the Boundary Theory to Ternary Phase Diagrams
3.5 Explanation of Rhines' Ten Empirical Rules for Constructing
Complicated Ternary Phase Diagrams with the Bounary Theory
3.6 Comparison of the Boundary Theory and the P-L's Contact Rule of
Phase Regions
References-3
Chapter 4
The Application of the Boundary Theory of Phase Diag-rams to the
Quaternary and Higher Number Component Phase Diagrams
4.1 Introduction
4.2 The Relationship among NPRs and their Boundaries in a Typical,
Iso-baric, Quaternary Phase Diagram
4.3 During Temperature Decreasing, Some Cases of Variations of the
NPRs
and their Boundaries, May be Encountered for Several Types of
Quaternary Isobaric Phase Diagrams
4.4 The Isobaric Quinary Phase Diagrams
4.5 Conclusion
References-4
Chapter 5 The Boundary Theory in Construction of Multicompo-nent
Isothermal Sections
5.1 The Relationship among Neighboring Phase Regions （NPRs） and Th-
eir Boundaries in Isobaric Isothermal Multicomponent Sections
5.2 The Non-Contact Phase Regions and the Boundaries between Them
Contents
5.3 Construction of an Isothermal Quinary Section, with Limited
Information
5.4 The Method of Constructing an Isothermal Eight-Component
section
5 5 Summary of Part TwoPart Three The Boundary Theory method
References-5
Chapter 6 The Boundary Theory of Multicomponent Isobaric Isopleth
Sections
6.1 Introduction
6.2 The Characteristics of Boundaries in Isopleth Sections for the
Case ofⅣ≥2 and R1≥1
6.3 The Characteristics of Boundaries in the Isopleth Section for
the Case of N≥2，R1=0，there is no Invariant Phase Transition between
the two NPRs
6.4 The Case 0f N≥2，R1=0，there is an Invariant Phase Transition
between the two NPRs．In this Case，there may be fl,Boundary Line or
a Boundary Point between two NPRs'
6.5 Example
6.6 The TheOrY of Two～Dimensional Sections of Isobaric
Multicomponent Phase Diagrams．
References-6
Chapter 7 The Application of the Boundary Theory to Isobaric Phase
Diagrams
7.1 Brief Review of the Application for the Boundary Theory
7.2 The Analysis of the Fe-Cr-C Isopleth Section。<br />    7.3 The Application of the Boundary Theory to Phase Diagram
Calculation
7.4 The Application of the Boundary Theory to Phase Diagram
Assessment．
7.5 The Application of the Boundary Theory to Phase Diagram
DeterlllinatiOn
7.6 The Application of the Boundary Theory to Phase Diagram
Education．
References-7
Summay of part two
Part Three The Boundary Theory and Calculation of High Pressure
Phase Diagrams
Chapter.8 The Boundary Theory for p-T-xi Multieomponent Phase
Diagrams
8.1 Introduction
8.2 The Theorem of Corresponding Relationship for p-T-xi
Multicomponent Phase Diagrams and Its Corollaries
8.3 The Relationship between R'1 and R1 in p-T-xi Multicomponent
Phase Diagrams
8.4 The Relationship among NPRs and Their Boundaries for the p-T-x
Binary Phase Diagrams
8.5 Relationship among NPRs and their Boundaries for the p-T-xi
Ternary Phase Diagram
8.6 The Application of Boundary Theory for Quaternary p-T-xi Phase
Diagrams
8.7 The Reliability of the Boundary Theory of Multicomponent p-T-xi
Phase Diagrams
References-8
Chapter 9 The Calculation of Unary High-Pressure Phase Diagra-ms
and the Boundary Theory of p-T Phase Diagrams of Multieomponent
Systems
9.1 Introduction
9.2 Calculation of Unary p-T Diagrams
9.3 The Boundary Theory of p-T Phase Diagrams of Multicomponent
Systems without Composition Variable
References-9
Chapter 10 Calculation of Binary High-Pressure Phase Diagrams
10.1 Principles for the Calculation of Binary Phase Diagrams at
Elevated Pressures
10.2 Calculation of the Standard Molar Gibbs Free Energy for the
Pure Components
10.3 Calculation of Activity Coefficientsγ i（T, po, xi） Of the/-tit
Component in the Equilibrium Phases
10.4 Partial Molar Volumes
10.5 Some Remarks on the Values of a andβ
10.6 Example-Calculation of the Cd-Pb Phase Diagram at High
Pressure
References-10
Chapter 11 The Calculation of High-Pressure Ternary Phase Dia-grams
11.1 The Characteristics of the Boundaries of the High-Pressure
Ternary Phase Diagrams, and the Basic Equations for Their
Calculation 
11.2 The Treatment of Thermodynamic Parameters for Ternary Systems
at High Pressure
11.3 Verification of the Estimation Method for the Excess Molar
Volume by Experiment
11.4 The Calculation of High-Pressure Phase Diagrams of Cd-Pb-Sn
and Cd-Sn-Zn Systems
11.5 Verification of Calculated High-Pressure Ternary Phase
Diagrams through Experimental Determination 
11.6 The Comparison between the Methods of Experimental Determina-
tion and Thermodynamic Calculation of High Pressure Phase Diagrams
References-11
Summary of Part Three
References of This Book
Important Symbols
Index
Annex
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